@Article{BourginAlvYanFacBau:2017:EfLeNu,
author = "Bourgin, E. and Alves, M. M. and Yang, C. and Fachini Filho,
Fernando and Bauwens, L.",
affiliation = "MBDA and {University of Calgary} and {University of Calgary} and
{Instituto Nacional de Pesquisas Espaciais (INPE)} and {University
of Calgary}",
title = "Effects of Lewis numbers and kinetics on spontaneous ignition of
hydrogen jets",
journal = "Proceedings of the Combustion Institute",
year = "2017",
volume = "36",
number = "2",
pages = "2833--2839",
keywords = "Jet ignition, Lewis number, Chain-branching, Hydrogen.",
abstract = "The transient process following a hydrogen leak into the
atmosphere initiates as a contact surface appears separating air
heated by the leading shock from hydrogen cooled by expansion.
Diffusion of heat and species produces reactive mixture,
potentially leading to ignition. Reactions being very
temperature-sensitive, their rate peaks close to the hot air-rich
side of the interface, where the small fuel concentration depends
upon the fuel Lewis number. If the Lewis number is less than
unity, diffusion brings in more fuel than temperature-controlled
chemistry consumes. If greater, diffusion does not bring in as
much fuel as chemistry would burn. Results from the current
analysis for multistep kinetics also show that the role of the H
Lewis number is crucial. In the short time limit, the evolution of
the diffusion layer appears as a perturbation superimposed to the
self-similar non-reactive diffusion solution. Initiation is very
slow compared with steps consuming one reactant and an
intermediate species, while some steps associated with termination
are extremely fast. The approximation being made, assuming
initiation much smaller than most rates, and termination much
faster, is very accurate since the corresponding ratios are of the
order of 10(5). The resulting problem still requires a numerical
solution. A time-splitting algorithm combines exact solutions to
three subproblems, avoiding issues such as stiffness of the
kinetics. The problem is formulated not in physical space but in
the similarity variable of the diffusion problem, hence avoiding
difficulties associated with the initial singularity when the
layer has zero thickness, and the resulting uncertainties. These
are distinct advantages over numerical simulations, which however
will retain a reasonable accuracy at later times. Results confirm
the role of the Lewis number. They also show two distinct regimes:
an early one mainly controlled by initiation, and a later one
controlled by chain-branching, with a sharp transition.",
doi = "10.1016/j.proci.2016.06.175",
url = "http://dx.doi.org/10.1016/j.proci.2016.06.175",
issn = "1540-7489",
language = "en",
targetfile = "bourgin_effects.pdf",
urlaccessdate = "27 abr. 2024"
}